Is hydrogen cyanide (HCN) a progenitor of acetonitrile (CH3CN) in the atmosphere?

Details Is hydrogen cyanide (HCN) a progenitor of acetonitrile (CH3CN) in the atmosphere? Is hydrogen cyanide (HCN) a progenitor of acetonitrile (CH3CN) in the atmosphere?

Mar 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985georl..12..117b&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 12, March 1985, p. 117-120. Research supported by the Chemical Manufacturers

Physics

12

Acetonitrile, Atmospheric Chemistry, Gas-Gas Interactions, Hydrocyanic Acid, Methyl Compounds, Biomass Energy Production, Mass Spectroscopy, Oxidation, Photodissociation, Stratosphere

Scientific paper

The possibility of a link between HCN and CH3CN in the atmosphere has been suggested recently. A new chemical analysis of this problem as well as model calculations indicate that, most probably, these gases are produced at the earth's surface and destroyed by oxidation in the middle atmosphere. The strength of the photodestruction of these two molecules seems to be weak. It is unlikely that HCN is an atmospheric source of CH3CN.

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