Iron mineralogy in sediments. A Mössbauer study

Physics

Scientific paper

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Scientific paper

Sequential chemical extraction is used to show that the Mössbauer spectrum of a lacustrine sediment is deceptively simple. Only two pairs of doublets arise when at least four chemically distinct forms of Fe are present. Recognition of this effect increases the power of Mössbauer spectroscopy as a tool in studies of the redox chemistry of Fe in sediments.

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