Ir Spectroscopy Study on the (HCl)N(H2O)M Aggregation in Helium Nanodroplets

Details Ir Spectroscopy Study on the (HCl)N(H2O)M Aggregation in Helium Nanodroplets Ir Spectroscopy Study on the (HCl)N(H2O)M Aggregation in Helium Nanodroplets

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confefe07n&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Matrix/Condensedphase

Scientific paper

The study of acid-water clusters is an active area of research due to its fundamental importance for chemistry. In particular the (HCl)N(H2O)M clusters have been extensively investigated both theoretically and experimentally as a benchmark system. Despite of the great effort devoted to its understanding HCl dissociation in water clusters is still not well understood. An IR-Spectroscopy study on (HCl)N(H2O)M embedded in helium nanodroplets will be presented. The H216O→H218O and isotopic substitution was used in the experiments to probe the bands in the 2650-2760 Cm-1 spectral range which has been object of some debate recently. The observed isotopic shifts for the different bands raise some new questions to be addressed.
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