Ion-pair formation in electron recombination with H3+

Details Ion-pair formation in electron recombination with H3+ Ion-pair formation in electron recombination with H3+

Nov 2006

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2006rspta.364.2999l&link_type=abstract

Royal Society of London Transactions Series A, vol. 364, Issue 1848, p.2999-3005

Physics

5

Ion-Pair State, Wave Packet Dynamics, H3+

Scientific paper

The process of resonant ion-pair formation following electron collisions with H3+ is studied. The relevant diabatic potential energy surfaces and the electronic couplings between these surfaces are calculated. The reaction is then described using a time-dependent approach with wave packets propagating on the coupled potentials. In order to describe the reaction, it is found necessary to include at least two dimensions in the model. The effects of the Rydberg states on the cross-section for this process are discussed.

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