Physics – General Physics
Scientific paper
Mar 1978
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1978phrva..17..889j&link_type=abstract
Physical Review A - General Physics, 3rd Series, vol. 17, Mar. 1978, p. 889-896. International Atomic Energy Agency
Physics
General Physics
22
Alkali Metals, Diatomic Molecules, Hydrogen, Ion Recombination, Ionic Reactions, Ionization Cross Sections, Electron Transitions, Metal-Gas Systems, Molecular Excitation, Pair Production, Reaction Kinetics
Scientific paper
The mutual neutralization and ion-pair-formation reactions in alkali-hydrogen diatomic systems are investigated in the low-energy region. The ionic-covalent exchange interaction in these systems at the diabatic curve crossings is calculated by the Landau-Herring method. The cross sections and reaction-rate coefficients of these reactions are calculated using the Landau-Zener theory, modified to include the underbarrier transitions and the effects of the variation of coupling interaction within the transition zone. For Cs-H system, the calculated recombination and ion-pair-formation cross sections are compared with the existing theoretical calculations and experimental data.
Janev R. K.
Radulovic Z. M.
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