Ion beam modification of reactively sputtered TiN thin films

Astronomy and Astrophysics – Astronomy

Scientific paper

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Scientific paper

A study of ion beam modification of structural and electrical properties of TiN thin films is presented. The layers were deposited by reactive ion sputtering on (100) Si substrates to a thickness of sim 240 nm. After deposition the structures were implanted with argon ions at 120 keV, to the fluences from 1 x10^15 -- 1 x 10^16 ions/cm^2. Structural analysis of the samples was performed by cross-sectional transmission electron microscopy, x-ray diffraction and Rutherford backscattering spectrometry. It was found that the as-deposited layers have a columnar structure, individual columns stretching from the substrate to the surface and being a few tens of nanometers wide. Ion irradiation rearranges their crystalline structure, which remains polycrystalline, but the columns are broken, and nanocrystals of the same phase are formed.

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