Physics – Chemical Physics
Scientific paper
2010-10-29
Physics
Chemical Physics
9 figures, 14 hfges
Scientific paper
The effect of conductivity switching of wideband polymers -plasticized PVC films under the influence of mono axial pressure is experimentally investigated. For various plasticizers the value of monoaxial pressure, causing jumps of conductivity on four and more orders, changes from units to hundreds bars, and the effect remains at a thickness of films of an order of hundreds micron, that is on two orders more than critical thickness for others wideband polymers. In addition to the reasons stated earlier on the interpretation of anomalies of plastic compounds conductivity, the phenomenological electron-molecular model of dynamic traps is considered, in which local transfer of charges is carried out by mobile segments of the plasticized polymer molecules.
Apresyan L. A.
Krystob V. I.
Vlasov D. V.
Vlasova T. V.
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