Intrinsic Hyperpolarizabilities as a Figure of Merit for Electro-optic Molecules

Details Intrinsic Hyperpolarizabilities as a Figure of Merit for Electro-optic Molecules Intrinsic Hyperpolarizabilities as a Figure of Merit for Electro-optic Molecules

2008-07-06

arxiv.org/abs/0807.0886v1

J. Phys. Chem. C 112, 7978-7982 (2008)

Physics

Chemical Physics

5 pages, 2 figures

Scientific paper

We propose the scale-invariant intrinsic hyperpolarizability as a measure of
the figure of merit for electrooptic molecules. By applying our analysis to the
best second-order nonlinear-optical molecules that are made using the present
paradigms, we conclude that it should be possible to make dye-doped polymers
with electrooptic coefficients of several thousand picometers per volt.

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