Interpretation of the measured rate of radiative association of CH3(+) and H2

Details Interpretation of the measured rate of radiative association of CH3(+) and H2 Interpretation of the measured rate of radiative association of CH3(+) and H2

Sep 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986phrva..34.1878b&link_type=abstract

Physical Review A - General Physics, 3rd Series (ISSN 0556-2791), vol. 34, Sept. 1986, p. 1878-1881.

Physics

General Physics

16

Association Reactions, Hydrocarbons, Hydrogen, Interstellar Chemistry, Molecular Ions, Radiative Recombination, Reaction Kinetics, Hydrides, Low Temperature, Methyl Compounds, Trapped Particles

Scientific paper

The trapped-ion measurements of Barlow et al. (1984) on CH3(+) + H2 yields CH5(+) + hnu (a reaction of interest in the chemistry of interstellar clouds) are reexamined. It is demonstrated that these measurements require the rate of the stabilizing radiative transition to be 0.00035 per sec. This high rate is attributed to an electron transition involving the state having CH4 + H(+) or CH3 + H2(+) as its dissociation products.

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