Inter-dimensional Degeneracies in van der Waals Clusters and Quantum Monte Carlo Computation of Rovibrational States

Physics – Quantum Physics

Scientific paper

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Scientific paper

10.1063/1.1941107

Quantum Monte Carlo estimates of the spectrum of rotationally invariant states of noble gas clusters suggest inter-dimensional degeneracy in $N-1$ and $N+1$ spacial dimensions. We derive this property by mapping the Schr\"odinger eigenvalue problem onto an eigenvalue equation in which $D$ appears as a continuous variable. We discuss implications for quantum Monte Carlo and dimensional scaling methods.

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