Intensities and N2 collision-broadening coefficients measured for selected H2O absorption lines between 715 and 732 nm

Physics – Optics

Scientific paper

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Absorption Spectra, Atmospheric Attenuation, Attenuation Coefficients, Infrared Spectra, Laser Spectroscopy, Nitrogen, Spectral Line Width, Water Vapor, Atmospheric Optics, Data Processing, Line Spectra, Remote Sensors, Spectral Resolution, Tables (Data), Ultraviolet Spectra, Voigt Effect

Scientific paper

Intensities and N2 collision-broadening coefficients are measured for 62 water vapor absorption lines between 715 and 732 nm potentially applicable to laser remote sensing of atmospheric water vapor. Absolute line strengths and widths were determined from spectra corrected for instrument resolution, air-path absorption and Lorentz and Doppler broadening for pure water vapor and water vapor-nitrogen mixtures in a multipass absorption cell with a base path length of 25 m (White cell). Line strengths are observed to range from 4 x 10 to the -25th to 4 x 10 to the -23rd kayser/molecule per sq cm, and collision broadening coefficients are found to be approximately equal to 0.1 kayser/atm.

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