Integrated band intensities of HO2NO2 at 220K.

Physics

Scientific paper

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Scientific paper

Integrated intensities of the 803, 940, 1304, 1397, 1728, and 3540 cm-1 bands of peroxynitric acid (HO2NO2) have been measured at 220K. Simultaneously-recorded u.v. (200-350 nm) and Fourier transform i.r. (700-4000 cm-1) spectra of low-pressure gas mixtures containing HO2NO2 predominantly were analyzed to determine the number densities of HO2NO2 in a multi-pass absorption cell within an error of approx. 10%. Absorption coefficients at 220K in the strong 803 cm-1 band, which should be useful in the interpretation of atmospheric spectra containing spectral features of HO2NO2, are also reported at high-resolution (0.003 cm-1).

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