Insight Into the Jahn-Teller Effect in the Nitrate Radical via the A-X Hot Bands

Details Insight Into the Jahn-Teller Effect in the Nitrate Radical via the A-X Hot Bands Insight Into the Jahn-Teller Effect in the Nitrate Radical via the A-X Hot Bands

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confewj06t&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Radicals And Ions

Scientific paper

Elucidation of the electronic states of the nitrate radical NO_3 remains an interesting puzzle for experimentalists and theorists alike. The A^2E" state is Jahn-Teller active and is pseudo-Jahn-Teller coupled to the ground X^2A_2' and excited B^2E' states. Analysis of the vibronic-allowed A-X transition spectrum shows vibronic bands exhibiting both static and dynamic distortions depending on the vibrational level of the upper A state. In the E"xe'=a_1"+a_2"+e" manifold, only the a_1" levels are accessible under ambient temperature experiments. We have gained new insight into the A state by examining the hot bands of NO_3, as previously dark levels of the A state become accessible. We present analysis of our hot band spectrum along with calculations of the upper A state levels.

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