Infrared Spectroscopy of Li(METHYLAMINE)n(NH3)m Clusters

Details Infrared Spectroscopy of Li(METHYLAMINE)n(NH3)m Clusters Infrared Spectroscopy of Li(METHYLAMINE)n(NH3)m Clusters

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..conferi04b&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Infrared/Raman (Vibrational)

Scientific paper

Recent work in our laboratory has led to the first size-selective infrared spectra of neutral Li(NH3)n clusters. Here we report on new work extending these studies to mixed cluster species, where ammonia derivatives such as methylamine (MA) replace some of the ammonia molecules. Spectra recorded using mass-selective IR depletion spectroscopy will be reported for Li(MA)m(NH3)n, with the emphasis on n + m = 4 clusters. The impact of replacing NH3 with bulkier ligands on the solvent structure will be described. In addition the IR spectrum of the smaller cluster Li(MA)(NH3) will be reported for the first time.

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