Infrared spectroscopy of crystalline and amorphous diacetylene (C4H2) and implications for Titan's atmospheric composition

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New laboratory spectra of crystalline and amorphous diacetylene ice have been recorded in the range of 7000-500 cm-1 (1.4-20 μm) to aid in the identification of solid diacetylene on Saturn's moon Titan. We have established that amorphous diacetylene ice is stable only at temperatures less than 70±1 K. With respect to observations on Titan, the best approach would be to utilize future space-based telescopes to search for the ν4 (3277/3271 cm-1) in absorption against the reflected light from the sun and the slightly weaker ν8 absorption bands (676/661 cm-1) in absorption against the continuum emission.

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