Infrared spectroscopy of carbo-ions. VI - C-H stretching vibration of the acetylene ion C2H2(+) and isotopic species

Details Infrared spectroscopy of carbo-ions. VI - C-H stretching vibration of the acetylene ion C2H2(+) and isotopic species Infrared spectroscopy of carbo-ions. VI - C-H stretching vibration of the acetylene ion C2H2(+) and isotopic species

Nov 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jchph..97.7111j&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 97, no. 10, p. 7111-7123.

Physics

Chemical Physics

30

Acetylene, Infrared Spectroscopy, Isotopes, Molecular Ions, Vibrational Spectra, Hydrogen Bonds, Molecular Oscillations, Molecular Structure

Scientific paper

The IR spectra of the band of the 2Pi-2Pi asymmetric hydrogen stretching vibration in the three isotopic acetylene ions C2H2(+) (nu3), (C-13)2H2(+) (nu3), and DCCH(+) (nu1) have been observed and analyzed. High-resolution IR spectra were recorded using a difference-frequency laser spectrometer as the tunable coherent IR source probing an ac glow discharge. Vibration-rotation interactions, the Renner-Teller interaction of perturbing states, plasma chemistry, and the relevance of this work to astrophysics are examined.

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