Infrared Laser Driven Double Proton Transfer. An Optimal Control Theory Study

Details Infrared Laser Driven Double Proton Transfer. An Optimal Control Theory Study Infrared Laser Driven Double Proton Transfer. An Optimal Control Theory Study

2009-12-09

arxiv.org/abs/0912.1715v1

Physics

Chemical Physics

9 figures

Scientific paper

Laser control of ultrafast double proton transfer is investigated for a two-dimensional model system describing stepwise and concerted transfer pathways. The pulse design has been done by employing optimal control theory in combination with the multiconfiguration time-dependent Hartree wave packet propagation. The obtained laser fields correspond to multiple pump-dump pulse sequences. Special emphasis is paid to the relative importance of stepwise and concerted transfer pathways for the driven wave packet and its dependence on the parameters of the model Hamiltonian as well as on the propagation time. While stepwise transfer is dominating in all cases considered, for high barrier systems concerted transfer proceeding via tunneling can make a contribution.

Affiliated with

Also associated with

No associations

Rating

Infrared Laser Driven Double Proton Transfer. An Optimal Control Theory Study does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Infrared Laser Driven Double Proton Transfer. An Optimal Control Theory Study, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Infrared Laser Driven Double Proton Transfer. An Optimal Control Theory Study will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-275962