Physics – Chemical Physics
Scientific paper
2002-10-29
Physics
Chemical Physics
8 pages, 5 figures
Scientific paper
10.1103/PhysRevE.67.046707
We have used Dynamic Monte Carlo (DMC) methods and analytical techniques to analyze Single-File Systems for which diffusion is infinitely-fast. We have simplified the Master Equation removing the fast reactions and we have introduced a DMC algorithm for infinitely-fast diffusion. The DMC method for fast diffusion give similar results as the standard DMC with high diffusion rates. We have investigated the influence of characteristic parameters, such as pipe length, adsorption, desorption and conversion rate constants on the steady-state properties of Single-File Systems with a reaction, looking at cases when all the sites are reactive and when only some of them are reactive. We find that the effect of fast diffusion on single-file properties of the system is absent even when diffusion is infinitely-fast. Diffusion is not important in these systems. Smaller systems are less reactive and the occupancy profiles for infinitely-long systems show an exponential behavior.
Jansen A. P. J.
Lukkien J. J.
Nedea S. V.
No associations
LandOfFree
Infinitely-fast diffusion in Single-File Systems does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Infinitely-fast diffusion in Single-File Systems, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Infinitely-fast diffusion in Single-File Systems will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-534261