Identification of forbidden vibration-rotation transitions in 15NH3

Details Identification of forbidden vibration-rotation transitions in 15NH3 Identification of forbidden vibration-rotation transitions in 15NH3

Jul 1984

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1984jmosp.106...64u&link_type=abstract

Journal of Molecular Spectroscopy, Volume 106, Issue 1, p. 64-71.

Physics

7

Scientific paper

Forbidden Δk - l = 3 vibration-rotation transitions have been observed in the ν4 band of 15NH3. The analysis of these transitions, together with previously published data on the allowed transitions, has made it possible to determine a set of molecular parameters, including for the first time the rotational constant C as well as the centrifugal distortion constants DK and HKKK, which are necessary for the calculation of energy levels. Some weak forbidden transitions in the ν2 band have also been observed.

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