Hyperfine spectra of CH3F nuclear spin conversion

Details Hyperfine spectra of CH3F nuclear spin conversion Hyperfine spectra of CH3F nuclear spin conversion

2000-04-19

arxiv.org/abs/physics/0004038v1

J. Phys. B: At. Mol. Opt. Phys., vol. 33 p. 1001 (2000)

Physics

Chemical Physics

12 pages + 7 eps figures, REVTEX

Scientific paper

10.1088/0953-4075/33/5/314

A theoretical model of hyperfine spectra of nuclear spin conversion of molecular isomers has been developed. The model takes into account the nuclear spin-spin and spin-rotation interactions, as well as the saturation of intramolecular mixing of molecular ortho and para states. The model has been applied to hyperfine spectra of nuclear spin conversion in ^{13}CH3F molecules subjected to an external electric field. Conditions under which the hyperfine structure in the spectra can be resolved have been determined.

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