Hydroxyl X2Pi pure rotational transitions

Details Hydroxyl X2Pi pure rotational transitions Hydroxyl X2Pi pure rotational transitions

Dec 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jgr....9720771g&link_type=abstract

Journal of Geophysical Research (ISSN 0148-0227), vol. 97, no. D18, p. 20,771-20,786.

Physics

6

Airglow, Electron Transitions, Hydroxyl Radicals, Molecular Rotation, Electric Moments, Schroedinger Equation, Transition Probabilities, Wave Functions

Scientific paper

We present a list of frequencies, term values, Einstein A values, and assignments for the pure rotational transitions of the X2Pi state of the OH molecule. This list includes transitions from 3 to 2015/cm for Delta-v = 0, v-double-prime = 0-4, and J-double-prime = 0.5-49.5. The A values were computed using recent advances in calculating wave functions for a coupled system and an experimentally derived electric dipole moment function (Nelson et al., 1990) which exhibits curvature.

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