Hydrogenolysis of Carbon-Oxygen Bonds in some Aromatic Compounds by Electrolysis

Details Hydrogenolysis of Carbon-Oxygen Bonds in some Aromatic Compounds by Electrolysis Hydrogenolysis of Carbon-Oxygen Bonds in some Aromatic Compounds by Electrolysis

Oct 1959

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1959natur.184.1064g&link_type=abstract

Nature, Volume 184, Issue 4692, pp. 1064-1065 (1959).

Physics

Scientific paper

WE have examined the reduction of anthraquinone and 9 : 10-diacetoxy-anthracene to 9 : 10-dihydro-anthracene and xanthydrol to xanthene by controlled potential electrolysis on a mercury cathode in dimethylformamide, phenol being present as proton donor in the experiment on the quinone. We have not previously encountered a report of carbon-oxygen scission brought about by such means.

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