High Resolution Infrared Spectroscopy of the PO_2 Radical

Details High Resolution Infrared Spectroscopy of the PO_2 Radical High Resolution Infrared Spectroscopy of the PO_2 Radical

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confewj03l&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Radicals And Ions

Scientific paper

The infrared absorption spectrum associated with the asymmetric stretching
fundamental of PO_2 (v_3) has been measured using high
resolution tunable diode laser spectroscopy. The free radical was formed in
large concentrations in a fast-flow system by reacting white phosphorus
vapour with atomic oxygen. More than 700 new lines have been assigned
between 1290 and 1350 Cm-1. Data was combined with infrared and LMR
lines, obtained from previous studies and simultaneously fitted using the
CALPGM suite. The precise constants derived definitively exclude a series
of unassigned transitions from belonging to the v_3 fundamental
band and potential assignments for that series are discussed.

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