High pressure luminescence of ZnTe:Cr2+ crystals

Details High pressure luminescence of ZnTe:Cr2+ crystals High pressure luminescence of ZnTe:Cr2+ crystals

Jan 2008

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2008njph...10a3023t&link_type=abstract

New Journal of Physics, Volume 10, Issue 1, pp. 013023 (2008).

Physics

1

Scientific paper

Results of the high pressure low-temperature luminescence measurements of ZnTe:Cr2+ crystals in a diamond-anvil cell are reported. The luminescence spectra associated with the 5E→ 5T2 transitions are split into three bands which exhibit quite different pressure coefficients from about 8 to 12 cm-1. The different values of the pressure coefficients are well explained by the Jahn Teller effect and pressure-dependent spin orbit interaction with second-order correction, associated with pressure-dependent admixture of the Te ligand wavefunction to the d-type wavefunction of the Cr2+ ion.

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