High-precision calculations of van der Waals coefficients for heteronuclear alkali-metal dimers

Physics – Atomic Physics

Scientific paper

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11 pages, 2 figs, graphicx.sty

Scientific paper

10.1103/PhysRevA.63.052704

Van der Waals coefficients for the heteronuclear alkali-metal dimers of Li,
Na, K, Rb, Cs, and Fr are calculated using relativistic ab initio methods
augmented by high-precision experimental data. We argue that the uncertainties
in the coefficients are unlikely to exceed about 1%.

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