Ground state wave function and energy of the lithium atom

Details Ground state wave function and energy of the lithium atom Ground state wave function and energy of the lithium atom

2006-01-30

arxiv.org/abs/physics/0601213v1

Physics

Atomic Physics

Scientific paper

10.1103/PhysRevA.73.022503

Highly accurate nonrelativistic ground-state wave function and energy of the lithium atom is obtained in the Hylleraas basis set. The leading relativistic corrections,as represented by Breit-Pauli Hamiltonian, are obtained in fair agreement with the former results. The calculational method is based on the analytical evaluation of Hylleraas integrals with the help of recursion relations.

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