Ground state of the hydrogen molecule in a strong magnetic field

Details Ground state of the hydrogen molecule in a strong magnetic field Ground state of the hydrogen molecule in a strong magnetic field

Oct 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997phrva..56.2510k&link_type=abstract

Physical Review A (Atomic, Molecular, and Optical Physics), Volume 56, Issue 4, October 1997, pp.R2510-R2513

Physics

9

General Molecular Conformation And Symmetry, Stereochemistry, Self-Consistent-Field Methods, Molecular And Chemical Processes And Interactions

Scientific paper

The ground state of a hydrogen molecule in magnetic fields is investigated using a fully numerical Hartree-Fock approach. We found that between 4.2×104 T and 3×106 T the ground state is 3Σ+u with very weak interaction between atoms. In this field region the hydrogen can form a superfluid phase, predicted earlier [Korolev and Liberman, Phys. Rev. Lett. 72, 270 (1994)]; the state 3Πu is metastable and may be responsible for the unknown excitonic line observed by Timofeev and Chernenko [JETP Lett. 61, 617 (1995)]. For magnetic fields stronger than 3×106 T the ground state is the tightly bound 3Πu.

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