Geophysical implications of reduction in thermal conductivity due to hydration

Physics

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Mineral Physics: General Or Miscellaneous, Physical Properties Of Rocks: Transport Properties, Tectonophysics: Heat Generation And Transport, Tectonophysics: Planetary Interiors (5430, 5724, 6024), General Or Miscellaneous: Techniques Applicable In Three Or More Fields

Scientific paper

Laser-flash measurements show that hydration lowers the lattice component of thermal diffusivity (D) for calcic and Fe-Mg garnets, and glasses. Hydration depresses D above the glass transition, suggesting that melts respond likewise. For garnets, which have a wide range of total water and OH- contents (X), ∂(lnD)/∂X = -0.003%/ppm H2O. For olivine and quartz, D is constant, but thermal conductivity (k = ρCPD) decreases because hydration lowers density (ρ) but negligibly changes heat capacity (CP). This finding is geophysically significant: specifically, it suggests that hydration leads to heat retention, promoting convective instabilities and melting.

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