Mathematics – Logic
Scientific paper
Apr 1990
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990gecoa..54.1025g&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 54, Issue 4, pp.1025-1035
Mathematics
Logic
2
Scientific paper
Mesozoic and Cenozoic carbonate-rich formations including Late Cretaceous phosphate deposits are exposed in a structural depression which is known as the Palmyra aulacogen. The bottom of this depression has been occasionally filled by water bodies during Quaternary humid episodes. The bottom of the depression now forms a sabkha as a consequence of modern semi-arid climatic conditions. Isotopic activity ratios and concentrations of U and Th were measured in bedrock formations, ground-waters, unsaturated soils, and in Quaternary lacustrine sediments cored in the sabkha in order to investigate the processes governing the fractionation and recycling of U and Th within the endoreic depression. The bedrock samples are close to secular equilibrium with the exception of phosphorites which show a 234 U deficit ( 234 U / 238 U = 0.83 ± 0.04). Upper soil horizons have a strong excess of 230 Th ( 230 Th / 234 U = 1.7 ± 0.2) as a consequence of U removal. The U loss occurs without fractionation ( 234 U / 238 U = 1.03 ± 0.01) as it is co-dissolved with the CaCO 3 matrix; this is also shown by an inverse relationship between CaCO 3 vs 232 Th in soils. Vertical profiles indicate transitional retention of U in the lower unsaturated soil horizons, where deficiency in 230 Th ( 230 Th / 234 U as low as 0.37 ± 0.02) and high U concentrations (up to ca. 100 · g ) characterize "secondary" co-precipitation of U and CaCO 3 which forms in response to downward decreasing pCO 2 during water percolation events. A rate of U removal of ca. 10 -4 to 10 -5 a -1 from the upper soil horizons and a residence time of approximately 40 to 50 ka of soil particles in the U-ablation zone were calculated using a simplified mathematical model based on the assumption that 230 Th remains immobile in the soils. The residence time of U corresponds to a rate of erosion of ca. 1 cm for 10 3 a. The activity ratios of the most recent lacustrine sediments of the sabkha (upper 2 m in cores) define a well correlated ( r > 0.97) "dilution curve" of the form: [ 230 Th / 234 U = (1.91 ± 0.03) ( 234 U / 232 Th -1 + 0.15 ±0.01]. This indicates that the radioisotopes inherited with the detrital fraction were diluted by an authigenic/early diagenetic phase of U fixation. A residence time for the diluting U (ca. 18,000 a) can be evaluated from the asymptote value (0.15 ± 0.01). This age corresponds to the last humid episode recorded in central Syria (the equivalent of the last glacial maximum at higher latitudes) which was associated with lacustrine sedimentation in the basin. Detrital particles eroded from the surrounding soils were then characterized by 238 U/ 232 Th and 230 Th/ 238 U ratios lower than those observed in modern upper soil horizons: i.e., by a longer residence time and a higher U-leaching rate during their pedologic cycle.
Causse Christiane
Gariepy Clément
Ghaleb Bassam
Hillaire-Marcel Claude
Vallieres Sylvain
No associations
LandOfFree
Fractionation and recycling of U and Th isotopes in a semi-arid endoreic depression of central Syria does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Fractionation and recycling of U and Th isotopes in a semi-arid endoreic depression of central Syria, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Fractionation and recycling of U and Th isotopes in a semi-arid endoreic depression of central Syria will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1380918