Fourier transform emission spectroscopy of the jet-cooled CCN free radical

Details Fourier transform emission spectroscopy of the jet-cooled CCN free radical Fourier transform emission spectroscopy of the jet-cooled CCN free radical

Feb 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990jchph..92.2244o&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 92, Feb. 15, 1990, p. 2244-2247. Research supported by the Petroleum Research

Physics

Chemical Physics

21

Cyanogen, Electron Emission, Emission Spectra, Fourier Transformation, Free Radicals, Infrared Spectroscopy, Acetonitrile, Dipole Moments, Electron Transitions, Ground State, Photolysis, Vibrational Spectra

Scientific paper

High-resolution Fourier transform spectrometry has been used to observe the A 2Delta-X 2Pi electronic transition of the CCN free radical in emission. The CCN was jet-cooled in He, in a corona-excited supersonic jet expansion of HC(N2)CN. The ground-state vibrational frequency spectroscopic constants derived from the 000-000, 000-001, 000-002, and 000-100 vibronic bands were nu(3) = 1050.7636 (6), 2nu(3) = 2094.8157(18), and nu(1) = 1923.2547(69)/cm.

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