Formation of ultracold, highly polar X1Σ+ NaCs molecules

Physics

Scientific paper

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Scientific paper

We present photoassociation spectroscopy of ultracold NaCs molecules formed in a dual-species magneto-optical trap. Excited-state molecules are formed in states correlating to the Na(3S1/2)+Cs(6P3/2) asymptote. We assign the most prominent observed vibrational progression to the Ω=2 long range state based on a comparison with ab initio potentials. Molecules are secondarily excited before decaying to deeply bound levels of the electronic ground X1Σ+ state where they are ionized and detected by time-of-flight mass spectroscopy.

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