Fluorescence emissions from mixtures of Hg with the noble gases

Physics – Chemical Physics

Scientific paper

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Fluorescence And Phosphorescence Spectra, Atomic Excitation And Ionization By Electron Impact

Scientific paper

Fluorescence emissions from mixtures of Hg with high pressure Xe, Kr, and Ar (~1 torr Hg, 103-104 torr noble gas) have been studied using a short-pulse relativistic electron beam as an excitation source. Hg-noble gas molecular bands were observed on the red sides of the Hg lines (1849 and 2537 A˚) as well as on the red sides of the Hg visible lines (7 3S1-->6 3P0,1,2). Temporal histories and production efficiencies of the molecular emissions were determined and a model was formulated for the time histories of the HgXe 2600 A˚ bands. Possible applications to high power laser systems are discussed.

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