Fluorescence efficiencies of electrons in molecular nitrogen and oxygen gases

Physics

Scientific paper

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Energy Conversion Efficiency, Fluorescence, Nitrogen, Oxygen, Gamma Rays, Ionization Cross Sections, Kinetic Energy, Oxygen Spectra, Secondary Emission, X Rays

Scientific paper

Fluorescence efficiencies of electrons in a large number of bands of the N2 First Positive and O2(+) First Negative groups lying in the 4900-10,500-A wavelength range have been investigated theoretically. The variation of transition moment with internuclear distance is taken into consideration. For the First Positive group of N2 the calculations are carried out at very low pressure as well as at 600 torr. In general the present values are higher than the experimental values, but in most of the cases fair agreement has been obtained. For the O2(+) First Negative group no direct experimental data are available. However, the present ratio of the total efficiency in the O2(+) First Negative group to the N2(+) First Negative group is found to be in good agreement with the experimental intensity ratio.

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