Fixed Area Mercury Electrode: a Sensitive Device for Electro Analysis

Details Fixed Area Mercury Electrode: a Sensitive Device for Electro Analysis Fixed Area Mercury Electrode: a Sensitive Device for Electro Analysis

Nov 1966

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1966natur.212..814d&link_type=abstract

Nature, Volume 212, Issue 5064, pp. 814-815 (1966).

Physics

Scientific paper

CONCENTRATIONS of electro-active species down to 10-4 mole/l. can be determined by conventional polarography1. Though this method offers a renewable surface, it has the disadvantage that the area is both variable and rather small (about 0.02 cm2). The potential sweep method2 enables concentrations as low as 10-5 mole/l. to be measured by increasing the area of the pool, but the area is not renewable and contamination of the pool electrode is therefore inevitable. This report describes a device combining the advantages of both techniques (Fig. 1).

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