Far-infrared absorption spectrum of the CH4-H2 gaseous mixture.

Details Far-infrared absorption spectrum of the CH4-H2 gaseous mixture. Far-infrared absorption spectrum of the CH4-H2 gaseous mixture.

Sep 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986jqsrt..36..239c&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 36, issue 3, pp. 239-247

Physics

5

Absorption Spectra:Molecules, Infrared Spectra:Molecules, Molecules:Absorption Spectra, Molecules:Infrared Spectra

Scientific paper

The rototranslational absorption spectrum of the CH4-H2 gaseous mixuture has been measured at five different temperatures from 296 to 140K, in the frequency range 150 - 850 cm-1. The absorption spectra due to the CH4-H2 interactions have been analysed considering only the quadrupolar induction of H2 on CH4 and the octupolar and hexadecapolar inductions of CH4 on H2. Under this assumption, the experimental data have been well accounted for, thereby providing a reliable way of predicting the CH4-H2 spectrum in a wide temperature range.

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