Experimental observation of the H2-N2 dimer spectrum near the pure rotational lines S0 and S1 of the H2 spectrum induced by collision with N2

Physics

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Dimers, Hydrogen, Molecular Collisions, Molecular Rotation, Molecular Spectra, Nitrogen, Line Spectra, Methane, Spectrum Analysis, Van Der Waals Forces

Scientific paper

Experimental observations of spectra of the H2-N2 dimer have been obtained between 300 and 650/cm at 79 K using a multiple reflection cell with an absorption path length of 84 m. Band frequencies of the present spectra are found to be well correlated with those of Titan spectra obtained by the Voyager IRIS, although the 600-610/cm line is less intense than that found in the Titan data. Discrepancies between the experimental data and the theoretical predictions of Borysow and Frommhold (1986) are pointed out.

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