Experimental determination of the ground-state inversion splitting in H3O(+)

Details Experimental determination of the ground-state inversion splitting in H3O(+) Experimental determination of the ground-state inversion splitting in H3O(+)

Apr 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985phrvl..54.1787l&link_type=abstract

Physical Review Letters (ISSN 0031-9007), vol. 54, April 22, 1985, p. 1787-1789.

Physics

55

Ground State, Hydronium Ions, Molecular Spectra, Infrared Spectroscopy, Laser Spectroscopy, Population Inversion, Rotational Spectra, Infrared Spectra

Scientific paper

The ground-state inversion splitting of the H3O(+) molecular ion has been determined to be 55.3462 + or - 0.0055/cm from the high-resolution laser infrared spectroscopy of the nu2 band. This has made it possible to predict accurately the ground-state inversion spectrum in the far-infrared region and the inversion-rotation spectrum in the millimeter-wave region, which may be used to detect this fundamental molecular ion in interstellar space.

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