Physics
Scientific paper
Jun 2011
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confetg09y&link_type=abstract
"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec
Physics
Electronic
Scientific paper
7-azaindole readily forms water clusters when seeded into a molecular beam. Interestingly, the addition of water considerably perturbs the excited state of 7-azaindole: the electronic origin of 7-azaindole(H_2O) is shifted drastically to lower energy, 1290 wn, relative to the origin of the bare molecule; furthermore, recent evidence indicates that 7-azaindole(H_2O) is of L_a character, contrary to the bare molecule. In this work, high resolution electronic spectra of 7-azaindole(H_2O) were measured in the presence of an external electric field , as a means to study water induced changes in the electronic distribution of 7-azaindole. Furthermore, the L_a/L_b character of the excited state of 7-azaindole(H_2O) was examined by recording similar spectra of isotopically labeled species.
T. B. C. Vu, I. Kalkman, L. W. Meerts, Y. Svartsov, C. Jacoby, and M. Schmitt, J. Chem. Phys. 128, 214311 (2008).
Pratt David W.
Young Justin W.
No associations
LandOfFree
Excited State Perturbations of 7-AZAINDOLE Mediated Through Micro-Solvation does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Excited State Perturbations of 7-AZAINDOLE Mediated Through Micro-Solvation, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Excited State Perturbations of 7-AZAINDOLE Mediated Through Micro-Solvation will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1001109