Etude cinétique de CVD de pyrocarbone obtenu par pyrolyse de propane

Details Etude cinétique de CVD de pyrocarbone obtenu par pyrolyse de propane Etude cinétique de CVD de pyrocarbone obtenu par pyrolyse de propane

2009-04-27

arxiv.org/abs/0904.4137v1

Physics

Chemical Physics

Scientific paper

High temeperature (900-1000\degree C) low pressure (<< 1 atm) pyrolysis of propane yields a pyrocarbon deposit, but also mainly hydrogen and hydrocarbons from methane to polyaromatics. 30 reaction products were exeperimentally quantified at different operating conditions. A detailed kinetic pyrolysis model (600 reactions) has been developed and validated based on the totality of experiments. This model includes a homogeneous model (describing the gas phase pyrolysis of propane) coupled with a heterogeneous model describing the pyrocarbon deposit.

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