Enrichment of CH3F nuclear spin isomers by resonant microwave radiation

Details Enrichment of CH3F nuclear spin isomers by resonant microwave radiation Enrichment of CH3F nuclear spin isomers by resonant microwave radiation

2002-08-29

arxiv.org/abs/physics/0208099v1

Physics

Chemical Physics

REVTEX, 14 pages + 6 eps figures

Scientific paper

10.1103/PhysRevA.67.033406

Theoretical model of the coherent control of nuclear spin isomers by microwave radiation has been developed. Model accounts the M-degeneracy of molecular states and molecular center-of-mass motion. The model has been applied to the 13CH3F molecules. Microwave radiation excites the para state (J=11,K=1) which is mixed by the nuclear spin-spin interaction with the ortho state (9,3). Dependencies of the isomer enrichment and conversion rates on the radiation frequency have been calculated. Both spectra consist of two resonances situated at the centers of allowed and forbidden (by nuclear spin) transitions in the molecule. Larger enrichment, up to 7%, can be produced by strong radiation resonant to the forbidden transition. The spin conversion rate can be increased by 2 orders of magnitude at this resonance.

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