Elementary thermodynamics of trapped particles

Physics – Physics Education

Scientific paper

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3 pages, no figures

Scientific paper

I develop simple thermodynamic relations for a collection of noninteracting classical particles confined in a harmonic trap. The volume of such a trap is not a good thermodynamic variable, so conventional expressions of the first law of thermodynamics and the ideal gas law must be modified. I use the frequency of oscillations about the minimum of the trap as an external parameter characterizing the confinement, and derive elementary relations between particle number, temperature, energy, oscillation frequency, and a generalized pressure, that are analogous to conventional thermodynamic relations for an ideal gas in a rigid volume. I also discuss heat capacities for trapped particles.

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