Electron transfer theory revisit: Quantum solvation effect

Details Electron transfer theory revisit: Quantum solvation effect Electron transfer theory revisit: Quantum solvation effect

2006-06-06

arxiv.org/abs/physics/0606058v1

Physics

Chemical Physics

5 pages, 3 figures. J. Theo. & Comput. Chem., accepted

Scientific paper

The effect of solvation on the electron transfer (ET) rate processes is investigated on the basis of the exact theory constructed in J. Phys. Chem. B Vol. 110, (2006); quant-ph/0604071. The nature of solvation is studied in a close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics are analyzed accordingly. The classical picture of solvation is found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.

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