Electron-temperature dependence of dissociative recombination of electrons with CO/+/./CO/n-series ions

Details Electron-temperature dependence of dissociative recombination of electrons with CO/+/./CO/n-series ions Electron-temperature dependence of dissociative recombination of electrons with CO/+/./CO/n-series ions

Mar 1981

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1981phrva..23.1481w&link_type=abstract

Physical Review A - General Physics, 3rd Series, vol. 23, Mar. 1981, p. 1481-1485.

Physics

General Physics

17

Carbon Monoxide, Electron Energy, Electron-Ion Recombination, Gas Dissociation, Recombination Coefficient, Recombination Reactions, Afterglows, Electron Capture, Laser Plasmas, Mass Spectrometers, Planetary Atmospheres

Scientific paper

The dependence on electron temperature of the coefficients for electron recombination with molecular cluster ions of the carbon monoxide series, CO(+).(CO)n, is determined. A microwave discharge lasting approximately 0.1 msec was applied in 5-20 Torr neon containing a few tenths percent CO in an afterglow mass spectrometer apparatus, and the time histories of the various afterglow ions were measured. Expressions for the dependence of the recombination coefficients of the dimer and trimer ions CO(+).CO and CO(+).(CO)2 are obtained which are found to be significantly different from those previously obtained for hydronium and ammonium series polar cluster ions, but similar to those of simple diatomic ions.

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