Electron scattering from H2(+) - Resonances in the Pi symmetries

Physics

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Electron Scattering, Electron States, Hydrogen Ions, Molecular Collisions, Molecular Ions, Autoionization, Dissociation, Ion Recombination, Molecular Orbitals, Photoionization

Scientific paper

The results of calculations for e(-) + H2(+) scattering in the region below the first excited state are presented. Three distinct and independent methods, close-coupling linear algebraic, effective-optical-potential linear algebraic, and R matrix, are employed to examine the collision at the highest level of sophistication and to provide a valuable check on the results of a single technique. For the 1Pi(u) and 3Pi(u) symmetries, strong interference effects are found between various autoionizing series, leading to significant variations of the resonance width with internuclear separation R. Such variations may have profound effects on such processes as photoionization, dissociation, and recombination. For the 1Pi(g) and 3Pi(g) symmetries, monotonic behavior of the width with R is observed and no evidence of strong interference effects or rapid changes is found.

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