Electron attachment to valence-excited CO

Details Electron attachment to valence-excited CO Electron attachment to valence-excited CO

1998-10-05

arxiv.org/abs/physics/9810009v1

Physics

Atomic Physics

Revtex file + postscript file for one figure

Scientific paper

10.1103/PhysRevA.59.4809

The possibility of electron attachment to the valence $^{3}\Pi$ state of CO is examined using an {\it ab initio} bound-state multireference configuration interaction approach. The resulting resonance has $^{4}\Sigma^{-}$ symmetry; the higher vibrational levels of this resonance state coincide with, or are nearly coincident with, levels of the parent $a^{3}\Pi$ state. Collisional relaxation to the lowest vibrational levels in hot plasma situations might yield the possibility of a long-lived CO$^-$ state.

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