Electrical double layer: revisit based on boundary conditions

Physics – Chemical Physics

Scientific paper

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Unfortunately, the previous version has a crucial misconcept. It is corrected

Scientific paper

The electrical double layer at infinite flat solid surface was discussed with
respect to the triple layer model. Charge density at the outer Helmholtz plane
is assumed to be zero usually. However, the assumption causes the position of
the outer Helmholtz plane to be obscure. The charge density was calculated and
the condition that the charge density is negligible was discussed.

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