Physics – Atomic and Molecular Clusters
Scientific paper
2009-10-08
AIP Conference Proceedings, Volume 1197, ed. by A.V.Solov'yov and E.Surdutovich (Melville, NY 2009)
Physics
Atomic and Molecular Clusters
Proceedings of ISACC 2009, The Fourth International Symposium "Atomic Cluster Collisions: structure and dynamics from the nucl
Scientific paper
Water clusters embedding a nitric acid molecule HNO3(H2O)_{n=1-10} are investigated via electrostatic deflection of a molecular beam. We observe large paraelectric susceptibilities that greatly exceed the electronic polarizability, revealing the contribution of permanent dipole moments. The moments derived from the data are also significantly higher than those of pure water clusters. An enhancement in the susceptibility for n=5,6 and a rise in cluster abundances setting in at n=6 suggest that dissociation of the solvated acid molecule into ions takes place in this size range.
Heinrich Jonathon
Kresin Vitaly V.
Moro Ramiro
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