Elasticity of aluminate, titanate, stannate and germanate compounds with the perovskite structure

Physics

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Scientific paper

Ultrasonic data for the velocities of a large number of perovskite-structure compounds have been determined as a a function of pressure to 6 kbar at room temperature for polycrystalline specimens hot-pressed at pressures up to 100 kbar in solid-media devices: ScAlO3, GdAlO3, SmAlO3, EuAlO3, YAlO3, CdTiO3, CdSnO3, CaSnO3 and CaGeO3. The elasticity data for these orthorhombic and cubic perovskites define systematic patterns on bulk modulus (KS)-volume (VO) and bulk sound velocity (υφ-mean atomic weight (M) diagrams which are insensitiv to the details of cation chemistry and crystallographic structure. These isostructural trends are used to estimate KS = 2.5 +/- 0.3 Mbar and υφ = 7.9 +/- 0.4 km/s for the perovskite polymorph of MgSiO3. On a Birch diagram of veloc vs. density, the perovskite data define linear trends which lead to erroneous estimates of velocity for MgSiO3 unless specific account is taken of ionic radius effects in isomorphic substitutions.

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