Effect of quasi-bound states on collisional redistribution

Physics

Scientific paper

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Atomic Collisions, Franck-Condon Principle, Light Scattering, Radiation Distribution, Rayleigh Scattering, Angular Momentum, Kinetic Energy, Thermodynamic Equilibrium

Scientific paper

An expression for the collisional redistribution of radiation due to states trapped by an excited state potential barrier in the limit of no subsequent collisions during the excited state lifetime is derived. By considering two simple models, three possible methods for qualitatively determining excited state well depths when no detailed knowledge of the ground or excited state interaction potentials exists a priori are suggested.

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