Doppler effect in fragment autoionization following core-to-Rydberg excitations of N2

Details Doppler effect in fragment autoionization following core-to-Rydberg excitations of N2 Doppler effect in fragment autoionization following core-to-Rydberg excitations of N2

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010njph...12f3030s&link_type=abstract

New Journal of Physics, Volume 12, Issue 6, pp. 063030 (2010).

Physics

2

Scientific paper

The autoionization of atomic fragments after core-to-Rydberg excitations in N2 has been studied using high-resolution electron spectroscopy. Doppler profiles are clearly observed on atomic autoionization peaks and show dependence on the symmetries of the excited states. It is demonstrated that information on the femtosecond dissociation dynamics after the Rydberg excitations can be gained through an analysis of the Doppler profiles.

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